黄铁矿与石英含金机理探讨   总被引：1，自引：0，他引：1       下载免费PDF全文

李国华  王大伟  王国富  黄志良 《地质找矿论丛》2001,16(3):149-154,160

从晶体结构化学角度出发，分析了金的电子结构及性质、黄铁矿晶体结构特点、二氧化硅的电子结构特点和石英晶体表面特征；探讨了Au^＋和Au^－离子形式分别替代Fe^2 离子和S^2-离子的形成机理以及以可见金方式在黄铁矿中的赋存机制；认为金在黄铁矿中的富集主要与其晶体结构有关，特别是与黄铁矿中Fe-S，S-S，Au-S和Fe-Au键的电子结构特点有关；应用稳定配合物的18电子规则和晶体生长的界面相模型探讨了石英含金机理；研究表明，石英含金不仅与石英表面的结构、内部缺陷和表面特征有关，还与石英生长的环境有关，尤其是与石英表面键的电子结构特点有关，并主要受石英晶体生长过程中的界面相的控制。  相似文献   

结合水对海积软土流变性质的影响   总被引：7，自引：2，他引：7  

何俊  肖树芳 《吉林大学学报(地球科学版)》2003,33(2):204-207

海积软土的变形和强度性质与时间有明显的相关性，其原因之一是其中含量较多的结合水。土在一定压力下先排出自由水，然后是结合水，结合水膜厚度发生改变。压力改变结合水膜厚度，引起粘滞系数改变。通过剪切增变试验得到了粘滞系数与压力呈线性关系。研究粘滞系数与压力之间关系对修正或建立较为符合实际的本构模型有一定意义。  相似文献   

MATLAB及其在扇区水泥胶结测井(SBT)资料成像处理中的应用     

张秀梅  陈立恪  达江 《物探化探计算技术》2005,27(4):292-294

MATLAB是集数学、图形处理和程序语言设计于一体的著名数学软件。它以矩阵为基本的数值计算单元,对数据进行分析处理、可视化等。利用这些优点,在MATLAB界面下编程处理扇区水泥胶结测井(SBT)现场采集的测量资料,最终以图像方式显示了套管井中0°~360°的套管波衰减数据。将处理结果与Atlas专用处理软件的处理结果进行分析对比,表明两者具有良好的一致性。  相似文献   

A mapping of the electron localization function for earth materials     

G. V. Gibbs  D. F. Cox  N. L. Ross  T. D. Crawford  J. B. Burt  K. M. Rosso 《Physics and Chemistry of Minerals》2005,32(3):208-221

The electron localization function, ELF, generated for a number of geometry-optimized earth materials, provides a graphical representation of the spatial localization of the probability electron density distribution as embodied in domains ascribed to localized bond and lone pair electrons. The lone pair domains, displayed by the silica polymorphs quartz, coesite and cristobalite, are typically banana-shaped and oriented perpendicular to the plane of the SiOSi angle at ~0.60 Å from the O atom on the reflex side of the angle. With decreasing angle, the domains increase in magnitude, indicating an increase in the nucleophilic character of the O atom, rendering it more susceptible to potential electrophilic attack. The Laplacian isosurface maps of the experimental and theoretical electron density distribution for coesite substantiates the increase in the size of the domain with decreasing angle. Bond pair domains are displayed along each of the SiO bond vectors as discrete concave hemispherically-shaped domains at ~0.70 Å from the O atom. For more closed-shell ionic bonded interactions, the bond and lone pair domains are often coalesced, resulting in concave hemispherical toroidal-shaped domains with local maxima centered along the bond vectors. As the shared covalent character of the bonded interactions increases, the bond and lone pair domains are better developed as discrete domains. ELF isosurface maps generated for the earth materials tremolite, diopside, talc and dickite display banana-shaped lone pair domains associated with the bridging O atoms of SiOSi angles and concave hemispherical toroidal bond pair domains associated with the nonbridging ones. The lone pair domains in dickite and talc provide a basis for understanding the bonded interactions between the adjacent neutral layers. Maps were also generated for beryl, cordierite, quartz, low albite, forsterite, wadeite, åkermanite, pectolite, periclase, hurlbutite, thortveitite and vanthoffite. Strategies are reviewed for finding potential H docking sites in the silica polymorphs and related materials. As observed in an earlier study, the ELF is capable of generating bond and lone pair domains that are similar in number and arrangement to those provided by Laplacian and deformation electron density distributions. The formation of the bond and lone pair domains in the silica polymorphs and the progressive decrease in the SiO length as the value of the electron density at the bond critical point increases indicates that the SiO bonded interaction has a substantial component of covalent character.  相似文献   

混凝土结构CFRP加固界面粘接质量DSSPI无损检测研究     

刘宝会  王喜强  秦玉文 《地震工程与工程振动》2006,26(3):162-164

本文将数字错位散斑技术引入CFRP加固混凝土界面粘接质量的检测。对预制缺陷模型检测的结果表明,该方法能够迅速准确地对CFRP加固粘接质量作出检测和评价,为混凝土结构加固界面粘接质量无损诊断提供一种新思路。  相似文献   

In-situ IR measurements of OH species in quartz at high temperatures   总被引：1，自引：0，他引：1  

S. Suzuki  S. Nakashima 《Physics and Chemistry of Minerals》1999,26(3):217-225

The nature of OH species in natural clear quartz was investigated by means of in-situ IR measurements over the temperature range –185 to 1000 °C. Reversible thermal behavior of OH species was examined for a sample pre-heated to 1000 °C for 1 hour. At room temperature, the IR spectrum of the quartz sample examined includes an intense absorption peak at 3379 cm^–1 which has been assigned to an OH stretching vibration associated with Al substituting for Si (OH(Al)). The major spectral changes of the OH(Al) bond involve a systematic shift of its peak position and a decrease in its integral absorbance with temperature. A quasi-linear increase of the peak position from –185 to 400 °C is interpreted to be due to the change in the vibrational frequency of OH(Al) with hydrogen bond (H bond) distance. At higher temperatures, the IR frequency shows only a slight change, indicating a small influence of the H bond. On the other hand, the gradual decrease of the integral absorbance of OH(Al) with temperature indicates a decrease of this defect’s molar absorptivity without any reduction in defect concentration. This is interpreted to result from a decrease in dipole moment of OH(Al) with temperature. A sudden shift of the vibrational frequency from 3396 to 3386 cm^–1 between 550 and 560 °C and a constant value of the integral absorbance from 535 to 570 °C were considered to be related to the change in H bond distance during the structural transformation of α-quartz to its β-form. The local environment of OH(Al) begins to change at temperatures below 570 °C, where the crystallographic α–β transition occurs. Received: 18 February 1998/ Accepted: 10 July 1998  相似文献   

Structural setting and tectonic evolution of the Apennine Units of northern Calabria     

Alessandro Iannace  Glauco Bonardi  Marco D'Errico  Stefano Mazzoli  Vincenzo Perrone  Stefano Vitale 《Comptes Rendus Geoscience》2005,337(16):373

A new structural–stratigraphic synthesis of the Apennine units of northern Calabria is presented. The Meso-Cenozoic successions are grouped into two tectonic units, named Pollino–Ciagola Unit (PCU) and Lungro–Verbicaro Unit (LVU), comprising terrains formerly attributed to five different tectonic units. FeMg carpholite and blue amphibole record HP–LT metamorphism in the LVU, followed by progressive decompression leading to final greenschist facies re-equilibration during dominantly extensional deformation. Final tectonic emplacement of the LVU over the PCU post-dated the metamorphism of the LVU and was accompanied by intense ductile deformation along zones of strain localisation in footwall rocks. All of the units were later affected by folding and minor thrusting during subsequent Apennine tectonics. To cite this article: A. Iannace et al., C. R. Geoscience 337 (2005).  相似文献   

祁连山石的晶体结构     

王立本  周康靖 《地质论评》1994,40(4):347-353

祁连山石是在我国青海省发现的一种新的硼碳酸盐矿物，已由国际矿物学会新矿物和矿物命名委员会批准。该矿物的晶体结构中，重碳酸根和正硼酸分子之间由氢键联接，其布具有带状特征，是一种新的结构类型。  相似文献   

冀东前寒武变质岩地区镁铁云母的晶体化学及红外吸收光谱     

贺义兴  胡大千 《矿物学报》1986,(1)

本文以镁铁云母成分和结构为基础,从化学键的角度讨论某些红外光谱的特征频率及其变化规律。反过来,再用这些规律,为阐述本地区变质作用的相对强度提供依据,并为找矿提供某些有益的信息。  相似文献   

Discrete element analysis of breakage of irregularly shaped railway ballast     

Ying Yan  Jinfeng Zhao 《Geomechanics and Geoengineering》2015,10(1):1-9

In order to reduce the maintenance costs of ballasted railway track and improve passenger comfort, the railway ballast particle breakage and its effect on track settlement need to be better understood. The failure process of individual railway ballast loaded between flat platens is simulated using the discrete element method, considering its irregular shape with the incorporation of parallel bonds. The tensile strength, the stress of a survival probability of 37% of samples, is obtained and compared with laboratory results from published literature for the verification of DEM simulations. The evolution to failure of the particle is understood from the stress-strain curve and progressive failure modes. The internal breakage mechanisms are analysed by tracking the accumulation of bond breakage number and the contact force distributions.  相似文献